I’ve been working since September 2007 (more or less) on an upcoming Silverlight book titled “Teach Yourself Silverlight in 24 Hours” at Sams. This book will be aimed at beginners with the technology (and maybe even beginners in programming). The reader is walked (with a lot of code samples and step-by-step examples) through most features of this amazing technology. The book has 24 chapters, each of them taking more or less (maybe rather a little more than a little less, to be honest :)) one hour to read. There are really tons of demos and cool examples, and so far the feedback I got has been really great.
Update: The book is now “Silverlight 2 Unleashed”. See the full Table of Content here.